The Absorption Spectrum of Hydrated Americium Chloride

Revisiting the pump–probe polarized transient hole-burning of the hydrated electron: Is its absorption spectrum inhomogeneously broadened?

Although simulations have predicted that the hydrated electron s absorption spectrum is inhomogeneously broadened, the experiments in the Literature that test this prediction have produced contradictory results. In this Letter, we describe new polarized transient hole-burning experiments on solvated electrons in both water and methanol. Although we chose excitation wavelengths that should have ...

Localizing of a Four-Level Atom via Absorption Spectrum

We propose a scheme for localizing an atom in a four-level configuration inside a classical standing wave field, conditioned upon the measurement of frequency of a weak probe field. In the classical standing wave field, the interaction between the atom and the field is position dependent due to the Rabi-frequency of the driving field. Hence, as the absorption frequency of the probe field is mea...

Controlling of Absorption and Dispersion Spectrum via Electromagnetically Induced Transparency

In this paper we examine the absorption and dispersion properties of a weak probe field via Electromagnetically Induced Transparency (EIT) in a four-level system. It is shown that under certain condition, using this model, the absorption cancellation is appeared and the medium becomes transparent to the weak probe field. It will be shown that the controlling of absorption and dispersion spectru...

Nuclear quantum effects in electronically adiabatic quantum time correlation functions: application to the absorption spectrum of a hydrated electron.

A general formalism for introducing nuclear quantum effects in the expression of the quantum time correlation function of an operator in a multilevel electronic system is presented in the adiabatic limit. The final formula includes the nuclear quantum time correlation functions of the operator matrix elements, of the energy gap, and their cross terms. These quantities can be inferred and evalua...

The unveiled states of americium.